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Neutralization heat
Chemistry

Neutralization heat

To demonstrate the enthalpy change arising from the neutralization of a strong acid with a strong base.

Reactions and energy changes
neutralisation; exothermic; enthalpy

The science behind this experiment

This experiment illustrates the typical reaction between acids and bases: an exothermic reaction, in which there is an evolution of heat.

Equipment used

  • Beaker 50 ml — CHE-002
  • Glass rod — PLA-004
  • Cylinder 100 ml — MEC-001
  • Thermometer — HEA-005

Chemicals and reagents

  • Hydrochloric acid — R:34-37 S:26-45
  • Sodium hydroxide — R:35 S:26-37/39-45

Questions for students

  • Describe what has happened.

What to expect

Every acid base reaction in aqueous solution gives the following neutralization reaction: H3O+ + OH– →2H2O. For which the enthalpy change is ∆H0 = – 55.8 K J mol1; the reaction is therefore exothermic and the system increases its temperature. Na+ + OH– + H3O+ + Cl → Na+ + Cl– + 2H2O. The reaction gives the salt and two molecules of water. The sodium and chloride ions take no part in the reaction and are therefore termed “spectator ions”.

Disposal

Dispose of the solution in the liquid wastes container.

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